Product ID:SOLVENT 51-L, CPS 211150
MSDS Date:11/18/1986
FSC:9150
NIIN:00N044038
MSDS Number: BSBWD

CHEVRON

RICHMOND, CA 94804-0054
US

Emergency Phone: 415-233-3737

Info Phone: 415-233-3737

Cage: 0AHD1

CHEVRON ENVIRONMENTAL HEALTH CENTER INC

4054 RICHMOND, CA 94804 US

Telephone: 800-582-3835

Cage: 0AHD1

SNIFFERS, SOLV HUFFERS) OF SOLV CNTNG TOLUENE HAVE

RTECS: 9999999ZZ

ON TOLUENE HAVE FAILED TO DEMONSTRATE TERATOGENICITY

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CAUSE DELAYED GROWTH & EXTRA RIBS IN OFFSPRING OF

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NON-TOX TO MOTHER. TOLUENE HAS NOT CONCLUSIVELY BEEN

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TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPROD

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HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO

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BY MED PERS. IF MED ADVICE CANNOT BE

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INGEST & SUBSEQUENT

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WHERE FEASIBLE & APPROP, REMOVE CONTAMD SOIL.

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LGR REL. CERTAIN AREAS HAVE SPECIAL AIR POLLUTION

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IF MATL IS REGULATED WHERE IT IS TO BE USED.

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IGNITED BY SOURCE SUCH AS PILOT LIGHTS, ELEC

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TO BE CARCIN. FEDERAL REGISTER, VOL 52,

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PARAFFINS (INCL NAPHTHENES)

Fraction By Weight: <10%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <95%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <0.02%

OSHA PEL 1PPM;5STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

IRREVERSIBLE HEARING LOSS WAS DETECTED. SAME

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EFT. SINCE LEVEL NEC TO PRDE HEARING LOSS IS > 7 X

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100 PPM IS NOT EXPECTED TO CAUSE ANY ADVERSE EFT.

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LD50 LC50 Mixture:LD50:(ORAL,RAT)5.3 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: EYES: MATL IS A PRIMARY
IRRITANT. APPLICATN INTO EYES OF RABBIT PRDCD SEV MEMB IRRIT W/OUT
CORNEAL INJURY. SKIN: MATL IS A PRIMARY IRRIT. APPLICATN ON TO SKIN
OF RABBITS PRDCD SEV ERYTHEMA & ED EMA. PRLNGD/FREQ RPTD CONT MAY
CAUSE IRRIT/MAY CAUSE SKIN TO BECOME CRACKED/DRY FROM DEFAT ACTION
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONOGRAPHS, SUPPLEMENT,
VOL 7, PG 120, 1987: GRP 1. NTP 6TH ANNUAL REPORT ON CARCIN, 1991:
KNOWN (ING 19)
Effects of Overexposure:HLTH HAZ: MATL. INHAL: BRTHG OF VAP @ CONC IN
AIR THAT EXCEED RECOM EXPOS STD MAY BE IRRITATING TO RESP TRACT &
CAN CAUSE CNS EFTS. INGEST: NOT EXPECTED TO HAVE ACUTE SYSTEMIC
TOX. SIGNS & SYMPS OF CN S EFTS MAY INCL 1/MORE OF FOLLOWING: HDCH,
DIZZ, LOSS OF APPETITE, WEAK & LOSS OF COORD. AFFECTED PERSONS
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FUSH IMMED W/FRESH WATER FOR @ LST 15 MIN WHILE HOLDING
LIDS OPEN. IF IRRIT PERSISTS, SEE A DR. SKIN: REMOVE CONTAMD CLTHG.
WASH SKIN THORO W/SOAP & WATER. SEE A DR IF IRRIT OCCURS. LAUNDER
CONT AMD CLTHG. INHAL: MOVE TO FRESH AIR. IFANY SYMPS CONTINUE, SEE
A DR. INGEST: GIVE WATER/MILK TO DRINK & TELEPHONE FOR MED ADVICE.
DO NOT MAKE PERSON VOMIT UNLESS DIRECTED TO DO SO (ING 13)

Flash Point Method:TCC
Flash Point:41.0F,5.0C
Lower Limits:1%
Upper Limits:6.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATL PRESENTS A FIRE HAZ. LIQUID QUICKLY
EVAP & FORMS VAP (FUMES) WHICH CAN CATCH FIRE & BURN W/EXPLOS
VIOLENCE. INVISIBLE VAP SPREADS EASILY & CAN BE (ING 18)

Spill Release Procedures:ELIM ALL SOURCES OF IGNIT IN VICIN OF SPILL/
REL VAP. STOP SOURCE OF LEAK/REL. CLEAN UP REL AS SOON AS POSS.
CNTN LIQ TO PVNT FURTHER CONTAM OF SOIL, SURF WATER/GROUNDWATER.
CLEAN UP SM SPILLS USING A PPROP TECH SUCH AS SORBENT
MATLS/PUMPING. (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:READ & OBSERVE ALL PREC ON PROD LBL.
DO NOT USE/STORE NEAR FLAME, SPARKS/HOT SURF. USE ONLY IN WELL
VENTD AREA. KEEP CONTR CLSD.
Other Precautions:DO NOT WELD, HEAT/DRILL CONTR. REPLACE CAP/BUNG.
EMPTIED CONTR STILL CNTNS HAZ/EXPLOSIVE VAPOR/LIQUID. CAUTION! DO
NOT USE PRESSURE TO EMPTY DRUM/EXPLOSION MAY RESULT. DO NOT GET IN
EYES, ON SKIN/ CLT HG. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESP PROT SUCH AS AN
ORG VAP CARTRIDGE RESP OR AN NIOSH/MSHA APPRVD AIR-SUPPLYING RESP
UNLESS VENT IS ADEQ TO KEEP AIRBORNE CONC BELOW RECOMMENDED EXPOS
STD.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS OF
THIS MATERIAL BELOW RECOMMENDED EXPOSURE STANDARD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV: [email protected]. EFTS OF OVEREXP: USUALLY EXPER COMPLETE RECOVERY
WHEN REMOVED FROM EXPOS AREA. PROD CNTNS TOLUENE. TOLUENE HAS BEEN
REPORTED TO DECR IMMUNOLOGICAL RESPONSES IN TEST ANIMALS. IT HAS
ALSO BEEN REPORTED THAT WHEN YOUNG RATS WERE EXPOSED TO 1000 PPM
TOLUENE FOR 14 HRS DAILY, FOR 2 WKS, (ING 4)

HCC:F3
Boiling Pt:B.P. Text:>225F,>107C
Vapor Pres:40@25C
Vapor Density:3.4
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:1.84(BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID
Percent Volatiles by Volume:>99

Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
AND WATER VAPOR; INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE.

Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE
CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGS. CONTACT LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR
APPROVED DISPOSAL OF THIS MATERI AL. DISPOSE OF I/A/W FED, ST & LOC
REGS.

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particular situation.